While Captain America is famously known as "The First Avenger" in the Marvel Cinematic Universe, he was not a founding member of the Avengers team in the comics. The team officially debuted in Avengers #1 in September 1963. The initial lineup was formed to combat Loki, who was manipulating the Hulk.
The actual founding members of the Avengers in the comics were:
Captain America joined the team later, in Avengers #4 (March 1964), after being discovered frozen in a block of ice and revived by the team. His historical significance as a World War II hero earned him the moniker "The First Avenger" within the Marvel Universe's timeline, but not as a founding member of the superhero group itself.
Pro tip: Many characters have held the mantle of Ant-Man and Captain America over the years. Hank Pym was the original Ant-Man and a founder. Steve Rogers was the original Captain America, but he joined the team after its initial formation.
Optional. A guide for new readers to understand the conventions, history, and storytelling techniques unique to Marvel Comics.
Optional but highly recommended. This collection focuses on Captain America's reintroduction to the modern world and his early adventures with the Avengers.
Essential. The very first issue where the Avengers team was formed. Reading the original source material provides the most accurate historical context.
Essential. This collection gathers the early issues of The Avengers, including the formation of the team and Captain America's introduction.
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